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PbO₂-Coated Titanium Anodes for Metal Electrowinning

YIANTENG engineers titanium-supported lead-dioxide anodes for copper, nickel, cobalt and other non-ferrous metal recovery. The substrate, conductive intermediate layer and lead-dioxide working coating are matched to electrolyte chemistry, current load and service strategy.

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Hydrometallurgy and Electrowinning

Hydrometallurgy recovers non-ferrous metals from chloride, sulfate or mixed chloride-sulfate solutions. After leaching and solution purification, direct current deposits the target metal on the cathode. The anode must carry continuous current, tolerate an aggressive electrolyte and preserve the designed electrode gap.

Traditional lead-alloy anodes change as they operate and can add weight, deformation, sludge and impurity-control work. A titanium-supported PbO₂ system separates the structural substrate from the active anodic surface and allows suitable electrodes to be inspected and recoated.

How Hydrometallurgical Electrowinning Works

Purified metal-bearing solution enters the cell. Metal ions receive electrons at the cathode and deposit as solid metal, while the insoluble anode sustains the counter-reaction and the lean electrolyte returns to the process circuit.

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Why PbO₂/Ti Instead of a Conventional Lead-Alloy Anode?

The choice is not simply “lead versus no lead.” It is a comparison between a consumable, heavy lead-alloy body and a dimensionally stable titanium structure carrying an engineered multilayer PbO₂ working surface.

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How YIANTENG Builds and Controls the Electrode

01Titanium preparationDegreasing, surface activation and dimensional inspection.
02Conductive interlayerA corrosion-resistant conductive layer is applied and thermally converted.
03PbO₂ base depositionA dense lead-dioxide foundation is electrodeposited onto the prepared surface.
04PbO₂ working coatingThe outer current-bearing layer is built to the specified loading and coverage.
05Final inspectionDimensions, coating condition and electrical response are checked before release.

Key Advantages for Electrowinning

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Lower Cell Voltage

Cell voltage can be approximately 0.05–0.1 V lower than with a lead-alloy anode, helping reduce power consumption during continuous electrowinning.

Longer Service Life

The corrosion-resistant PbO₂ working surface protects the reusable titanium structure, extending service intervals and reducing electrode changes and production downtime.

Lighter, Easier Handling

The titanium mesh structure is considerably lighter than a solid lead-alloy electrode, making installation, lifting and routine cell maintenance easier.

Cleaner Electrolyte

The insoluble coating limits lead-sulfate shedding and contains no Sn, Sb or Ag alloy additions, reducing sludge, tank cleaning and anode-derived contamination.

More Uniform Electrowinning

The open mesh promotes electrolyte circulation and more even current distribution, supporting steadier deposition and more consistent cathode-metal quality.

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